通过有机配体界定的锌的磷酸化合物拓扑结构(晶(11)

FanandHanson

bythecombinationoftwobuildingblocks,the4-ringandthetriplefused4-ring.Conclusion

Inthispaper,sixtailoredinorganiczincphosphatemotifsareobservedwhentheligandsL1-L5modifythezincions.Atthepresenttime,thesize,Zn/Pratio,andtheframeworkofthezincphosphatephasescannotbecontrolledasdesired.However,potentiallyporousmaterialscanbeexpectedwhiletheZn-Pphaseislinkedbyrigidligands.Wearecurrentlyinvestigatingtheuseofrigidligandsintheconstructionofsuchporousmaterials.

Acknowledgment.WethankR.J.ReynoldsforsupportofthisworkthroughaMcNairpostdoctoralfellowshiptoJ.F.WethanktheNSF(GrantCHE-0131128)forfundingthepurchaseoftheOxfordDiffractionXcalibur2singlecrystaldiffractometer.WethankMs.LiangmingHufortheTGA.WethankMarkElvingtonfortheemissionspectra.

SupportingInformationAvailable:FigureS1,showingthepackingdiagramof3,andX-raycrystallographicfilesinCIFformat.ThismaterialisavailablefreeofchargeviatheInternetat.

IC050314T

7008InorganicChemistry,Vol.44,No.20,2005