通过有机配体界定的锌的磷酸化合物拓扑结构(晶(10)

NoWelZincPhosphateTopologies

Scheme3.SchemefortheFormationofCompounds1-6from4-Rings

a

a

Thenewconnectionsarerepresentedbyshortbars(Zn:pink.P:yellow).

generatesthe4.8-chainasobservedin2.When8-ringsareconnectedintwodirections,then,4.82-sheetsareobtainedasobservedin4and5.Theladderstructurecanalsobeconsideredasapossibleintermediateintheformationofthe4.8-chain.Forexample,iftwoofeveryfourrungsofa4-ringladderarecleaved,a4.8-chainresults.Similarly,the63-sheetcanbeobtainedviathecleavageandconnectionpatternshowninScheme3.Theladderstructuremayalsobecleavedtogeneratethealternatingtriple4-ring/4-ringpatternof3.Alternatively,theinorganicmotifin3canbeconstructed

InorganicChemistry,Vol.44,No.20,2005

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